fluidized bed reactor applications

This results in the medium then having many properties and characteristics of normal fluids, such as the ability to free-flow under gravity, or to be pumped using fluid type technologies. using fluidized bed processing systems but gases can also be changed on powders through the fluidized bed. In this type of reactor, a fluid (gas or liquid) is passed through a solid granular material (usually a catalyst possibly shaped as tiny spheres) at high enough speeds to suspend the solid and cause it to behave as though it were a fluid. 4. Fluidized bed electrodes (FBEs), which were discovered in the late 1960s, are 3D (three-dimensional) particle electrodes. 1997, 36, 4549-4556). In the disengagement zone the gas composition is analyzed by chromatography. Once this minimum velocity is surpassed, the contents of the reactor bed begin to expand and swirl around much like an agitated tank or boiling pot of water. Fluidized beds are extensively utilized in mechanical processes, energy technology and processing industries (Vollmari et al, 2016). Some of the excellent features of FBR include low operating cost ( Ahmadi et al., 2015 ), high resistance to system upsets ( Brackin et al., 1996 ), high mass transfer rates and uniform mixing ( Andalib et al., 2014 ). Eng. Some advantages of using a fluidized bed include uniform particle mixing and temperature gradients. Author information: (1)Department of Chemical Engineering, Faculty of Engineering, University of Malaya, Kuala Lumpur 50603, Malaysia. Multiphase flow and fluidization of fine particles has a wide application in the industry. As the fluid velocity is increased, the reactor will reach a stage where the force of the fluid on the solids is enough to balance the weight of the solid material. A fluidized bed reactor (FBR) is a type of reactor device that can be used to carry out a variety of multiphase chemical reactions. A liquid granule suspension is sprayed in from above, in the air stream it turns into solid granulate and collects on the top of distributor plate and the exhaust air flows through a filter for cleaning. primarily in the temperature range up to 1100 °C offer a variety of new applications. They are also used in the oxidation of naphthalene to phtalic anhydride, roasting of sulfide ores, coking of petroleum residues, and the calcination of limestone. 1997, 36, 4549-4556). Sci. presenté par : ABDELGAWAD Borhan en vue de l’obtention du diplôme de : Maîtrise ès sciences appliquées a été dûment accepté par le jury d’examen constitué de : M.FRADETTE Louis, Ph.D, président M.CHAOUKI Jamal, Ph.D, membre et directeur de recherche In the present study a novel directly-irradiated fluidized bed autothermal reactor (DIFBAR) for solar-driven chemical processing is presented. Many industrially produced polymers are made using FBR technology, such as rubber, vinyl chloride, polyethylene, styrenes, and polypropylene. Tavoulareas, S. Gas Mixing in Circulating Fluidized Beds. One of the most common reactors in the chemical industry, for use in heterogeneous catalytic processes, is the packed bed reactor. Packed Bed Reactor. 2002, 57, 4797-4807; AIChE J. Fluidized bed technology offers especially many potential process benefits when a good gas/solids contact is desired. Res. This reactor possesses an overall volume of 100 L with the expanded bed volume taking up 30 L. Two radiation furnaces (64 kW) are used to heat the reactor. Chem. Cracking of Hydrocarbons (Fluid Catalytic Cracking, etc). The material that follows is based upon what is seemingly the best model of the fluidized-bed reactor developed thus far–the bubbling bed model of The Minimum Fluidization Velocity O The Ergun equation in (1) can be written as, ∆ = − + ( − ) ----- (4) O At the point of minimum fluidization, the weight of the bed just equals the . [3] This FBR and the many to follow were developed for the oil and petrochemical industries. [1] The fluid is then forced through the distributor up through the solid material. 4.1. [2] One of the first United States fluidized bed reactors used in the petroleum industry was the Catalytic Cracking Unit, created in Baton Rouge, LA in 1942 by the Standard Oil Company of New Jersey (now ExxonMobil). The article gives an overview on fundamentals and applications of fluidized‐bed technology. Fluidized bed reactor (FBR) has proven to be an effective reactor in the applications of both AOPs (Tisa et al., 2014) and biological processes (Zou et al., 2016). Fluidized bed reactors are a relatively new tool in the chemical engineering field. Methanol to gasoline and olefin processes. A novel induction heating fluidized bed reactor: Its design and applications in high temperature screening tests with solid feedstocks and prediction of defluidization state Mohammad Latifi Dept. Fluidized Bed Reactors Fluidized bed reactors are used extensively in the chemical process indus-tries. This also provides a simple alternative to Fluoride abatement while … Petroleum … The material that follows is based on what is seemingly the best model of the fluidized-bed reactor developed thus far--the bubbling-bed model of Kunii and Levenspiel. Energy-saving potential up to 40% and numerous other benefits make the fluidized bed reactor a true alternative to the rotary furnace (see table for details). A fluidized bed reactor (FBR) is a type of reactor device that can be used to carry out a variety of multiphase chemical reactions. Coal combustion. using fluidized bed processing systems but gases can also be changed on powders through the fluidized bed. 2002, 57, 4797-4807; AIChE J. the most disadvantage with fluidized-bed reactors is that they require fairly little particles (2–3 mm) to reduce heat/mass transfer effects: this leads to costly needs for grinding lignocellulosic biomass. The Fluidized Bed Reactor (FBR) chamber is a versatile particle coating option for the Beneq TFS 200. bubbling and slugging) fluidized beds, whereas they overlap substantially with transport reactors. Fluidized bed reactors are heterogeneous catalytic reactors in which the mass of catalyst is fluidized. Application of a Fluidized Bed Reactor in the MTO (Methanol to Olefin) Process: Preparation of Catalyst and Presentation of a Kinetic Model. Fluidized bed reactor – an overview 1. . The employment of a high-performance fluidized bed reactor for process applications requires close cooperation between the system builder and the customer. The fluidized-bed reactor is the centerpiece of industrial fluidization processes. Fluidized bed reactors are commonly used in catalytic cracking processes. In this type of reactor, a fluid (gas or liquid) is passed through a solid granular material (usually a catalyst possibly shaped as tiny spheres) at high enough speeds to suspend the solid and cause it to behave as though it were a fluid. 5. The team at Envirogen has a long history of harnessing the science of microbiology to produce high-performance Fluidized Bed Reactor (FBR) systems engineered to eliminate even the most difficult chemicals, such as selenium, nitrate, perchlorate, BTEX and many other, from aqueous streams, providing high-quality, potentially recyclable water and potable water. Current Applications for Fluidized Bed Reactors FBRs are everywhere in the Process Industries. The industrial fluidized bed process ranges from simple applications like drying, cooling, pneumatic transport of powders, etc. This reactor provides easy loading and removing of catalyst. With the FBR chamber you get : an easy-to-mount, easy-to-remove reactor assembly; truly conformal coating of fine powders; a chamber-in-chamber design providing the … Fluidized bed reactor Level measurement and filter monitoring in granulate production in the fluidized bed process. 1199-1208 1199 APPLICATION OF STEREOLOGY FOR TWO-PHASE FLOW STRUCTURE VALIDATION IN FLUIDIZED BED REACTORS by Stanislaw ANWEILER* and Maciej MASIUKIEWICZ You want to learn more?Please call +49 2845 930-115, send us an e-mail or contact one of our experts with any question you may have. Fluidized-Bed Combustion Technology. In this type of reactor, a fluid (gas or liquid) is passed through a granular solid material (usually a catalyst possibly shaped as tiny spheres) at high enough velocities to suspend the solid and cause it to behave as though it were a fluid. 6079, Succ. Solids Mixing in Circulating Fluidized Beds. Introduction The earliest fluidized bed reactors used for the catalytic cracking of hydrocarbons dating from the early 1940's operated at high superficial gas velocities now associated with the regime of fast fluidization. solid and liquid or gas properties. Many metallic oxides, catalysts, hydroxides, silicates, salts, sulfates, carbon blacks, pigments and graphites are roasted, calcined, reduced, oxidized, activated, passivated, chlorinated, dried, tempered, etc. The first work on modeling a gas-phase polymerization reactor is due to Choi and Ray (1985), which had the objective of understanding the reactor dynamic behavior. Gas Mixing in Bubbling Fluidized Beds. Chapter 3. (1991.) Consequently, a detailed design of a fluidized bed reactor that would allow flexible operation at high temperature and high pressure at several gas velocities will be conducted in order to serve for the future development of new hydrodynamic models. Applications: Today fluidized bed reactors are still used to produce gasoline and other fuels, along with many other chemicals. 6.2. 6.3. Author information: (1)Department of Chemical Engineering, Faculty of Engineering, University of Malaya, Kuala Lumpur 50603, Malaysia. The employment of a high-performance fluidized bed reactor for process applications requires close cooperation between the system builder and the customer. This takes place under consideration of the specific requirements of the respective chemical process, the material properties and the required product parameters and quality grades. A circulating fluidized-bed (CFB) reactor is extremely the same as a bubbling fluidized-bed reactor. dynamic models for fluidized-bed polymerization reactors. Chem. 6079, Succ. Sci. The fluidized-bed reactor plays important roles in the mixing of the catalyst and pyrolyzed products of cellulose and catalyst circulation between reduced and oxidized states. Fluidized bed electrodes (FBEs), which were discovered in the late 1960s, are 3D (three-dimensional) particle electrodes. The distinguishing feature of a fluidized bed reactor is that the solids bed of catalytic particles is supported by an upward flow of gas. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.) The present method utilizes fluidized bed reactor using red-mud as bed material thereby utilizing wastes of aluminium industry. Applicability of fluidized bed reactor in recalcitrant compound degradation through advanced oxidation processes: a review. A fluidized bed reactor (FBR) is a type of reactor device that can be used to carry out a variety of multiphase chemical reactions. Using a thermogravimetric analyser (TGA) as a fixed bed and the TGFBR as a fluidized bed, 6. This reactor possesses an overall volume of 100 L with the expanded bed volume taking up 30 L. Two radiation furnaces (64 kW) are used to heat the reactor. H. Shih DOI: 10.4236/msa.2019.103021 256 Materials Sciences and Applications The spherical shape of aluminum powders in a gas phase fluidized bed can help With the FBR chamber you get : an easy-to-mount, easy-to-remove reactor assembly; truly conformal coating of fine powders; a chamber-in-chamber design providing the … Measuring task: Level measurement and filter monitoring. Due to the advantages of fluidized bed reactors, a large amount of research is devoted to this technology. The product is removed from the fluidized-bed zone by a system of discharge vases, which operates in cycles determined by the production rate of the reactor. Using this novel fluidised bed, gravimetric measurements and high heating rate, the thermal conversion of biomass was investigated. Typical applications (reaction character), including combustion of carbon, capture Eng. This allows for extensive mixing in all directions. data for gas-solid reactions under isothermal conditions, a thermogravimetric fluidized bed reactor (TGFBR) was designed. Process data. Application of Stereology for Two-phase Flow … THERMAL SCIENCE: Year 2016, Vol. A uniform stream of air is fed up through a distributor plate at the bottom of the fluidized bed reactor. Depending on the operating conditions and properties of solid phase various flow regimes can be observed in this reactor. 20, No. At lower fluid velocities, the solids remain in place as the fluid passes through the voids in the material. After their Expert in thermal cleaning solutions and fluid bed process technology boosts presence in North America, TWIST: Research project for thermochemical energy storage systems, SCHWING Technologies opens location in the USA, Production of carbon modifications → Carbonizing / Engineering material, batteries, Graphite, Soot → Pigments / Surface modifications / Batteries, tire industry, Active carbon → Activation / Desorption / Water plants, chemical dry-cleaning, clothing, Titanium dioxide → Tempering / Coating / Pigment production, paints and varnishes, crèmes, Catalyst → Recycling / Oxidation / Reduction, Quartz sand → Deactivation of binding agents / foundry sand, Silicon → Calcining / Surface modifications / Recycling cutting waste, solar cells, silanes, Silicon dioxide → Silicic acid / Optical waveguides, data transmission, Salts → Carbonates / Fuel cells, glass, ceramics, enamel industry, Metal oxides → Tempering / electrical technology, batteries, catalysts, Gas/Gas reactions → catalytic / Solar industry, acid production. Most current research aims to quantify and explain the behavior of the phase interactions in the bed. a stable, well fluidized layer is present. The Fluidized Bed Reactor (FBR) chamber is a versatile particle coating option for the Beneq TFS 200. The solid substrate (the catalytic material upon which chemical species react) material in the fluidized bed reactor is typically supported by a porous plate, known as a distributor. The reactor used in this particular UT -ORNL collaborative research project has a cylindrical body and a tapered, conical bottom (see Figure 2). (2011). Industrial Applications. Accepting considerable advantages of circulating fluidized beds (CFBs) over the conventional fluidized beds, there has been numerous studies on CFBs concentrating primarily on the development of gas−solid circulating fluidized beds (GSCFBs). The bubbling fluidized bed is doubtless the foremost standard reactor for quick shift. of Chemical Engineering, Ecole Polytechnique de Montreal, C.P. A fluidized bed is a physical phenomenon occurring when a quantity of a solid particulate substance (usually present in a holding vessel) is placed under appropriate conditions to cause a solid/fluid mixture to behave as a fluid. The SCHWING fluidized bed process technology is predestined for gas-solids reactions. Fluidized bed reactor – an overview. Chem. International Journal of Chemical Reactor Engineering 2013 , 11 (1) , 443-452. This book focuses on the design and operation of fluidized beds in many different industrial processes, emphasizing the rationale for choosing fluidized beds for each particular process. of Chemical Engineering, Ecole Polytechnique de Montreal, C.P. The team at Envirogen has a long history of harnessing the science of microbiology to produce high-performance Fluidized Bed Reactor (FBR) systems engineered to eliminate even the most difficult chemicals, such as selenium, nitrate, perchlorate, BTEX and many other, from aqueous streams, providing high-quality, potentially recyclable water and potable water. One of the several applications fluidized beds are utilized for is chemical reactors. One method for producing and drying granulates is the fluidized bed process. [6], As in any design, the fluidized bed reactor does have its draw-backs, which any reactor designer must take into consideration.[6]. Their model included the mass and heat transfer effects of the fluidized bed and a basic kinetic scheme. The heat of reaction of the exothermal hydration reaction is removed by water, evaporating in a cooling coil, immersed in the fluidized bed. fluidized bed bed reactor gas Prior art date 2009-02-26 Legal status (The legal status is an assumption and is not a legal conclusion. While bubble sizes and velocities for low velocity bubbling fluidized beds have been examined in several studies, there have been only few studies about bubble behavior at superficial gas velocities up into the turbulent regime. Res. Gas Mixing in Fluidized‐Bed Reactors. Used in these applications, fluidized bed reactors allow for a cleaner, more efficient process than previous standard reactor technologies. In this type of reactor, a fluid (gas or liquid) is passed through a granular solid material (usually a catalyst) at high enough velocities to suspend the solid and cause it to behave as though it were a fluid. 2.2.2 SPHERILENE Process 2003, in press) is adapted to evaluate the performance of a fluidized-bed membrane reactor for steam reforming with oxygen input in a large-scale unit (16 m high and 2 m wide) described by Adris and Grace (Ind. A result of the mixing is excellent temperature stability and increased mass-transfer and reaction rates. As a result, FBRs are used for many industrial applications. 2003, in press) is adapted to evaluate the performance of a fluidized-bed membrane reactor for steam reforming with oxygen input in a large-scale unit (16 m high and 2 m wide) described by Adris and Grace (Ind. In current applications, circulating bed reactors encompass primarily Groups A and B In the fluidized bed the product (solids particle) is held in a vertical “gas flow suspension” and thereby ensures optimal process management. Depending on the operating conditions and properties of solid phase various flow regimes can be observed in this reactor. Heat and Mass Transfer in Fluidized‐Bed Reactors. Micro Fluidized Bed Reaction Analyzer (MFBRA), which was developed by IPE, CAS, employing micro fluidized bed as reactor to strength mass and heat transfer, realized the plug flow of gas and mixing flow of solid in the reactor. this case is named elutriation. To enable us to respond to your questions or specific demands with custom-tailored information we ask you to please use the inquiry form “Fluidized Bed Process Technique”. Phthalic anhydride synthesis. Fischer-Tropsch Synthesis. in a compact system the separation (retention) of the solid particles from the waste gas works well and the waste gas is recirculated or can be discharged to the atmosphere. Nearly all of the significant commercial applications of fluidized-bed technology concern gas-solid systems, so these are treated in this section. 1. the product flows well in continuous or batch operation thus enabling the discharge of the product. Tisa F(1), Abdul Raman AA(2), Wan Daud WMA(1). This process, known as fluidization, imparts many important advantages to an FBR. Fluorine is a toxic and corrosive chemical with a threshold limit value (TLV) of 1 ppm. A fluidized bed reactor (FBR) is a type of reactor device that can be used to carry out a variety of multiphase chemical reactions. fluidized bed. The first fluidized bed gas generator was developed by Fritz Winkler in Germany in the 1920s. This takes place under consideration of the specific requirements of the respective chemical process, the material properties and the required product parameters and quality grades. This type of reactor is used both in synthesis as well as in effluent treatment and catalytic combustion. [8] This will enable chemical engineers to design better, more efficient reactors that may effectively deal with the current disadvantages of the technology and expand the range of FBR use. Trickle Bed Reactor: A packed bed where a liquid reactant is fed from the top, wetting catalytic pellets & a gas reactant, fed either from top or the bottom, flows through the void spaces between the pellets. Unlike pack beds that have poor mixing , fluidized normally allows for a more uniform product compared to other reactor … This stage is known as incipient fluidization and occurs at this minimum fluidization velocity. Heterogeneous Catalytic Gas‐Phase Reactions. Fluidized bed process technology is a very versatile technology that can be used to implement and optimize many chemical and physical processes with powdery materials. The gaseous reactant must be absorbed & transported cross the liquid film to the catalytic sites at the surface of the pellets. As a core application, this technology is used in the area of surface modification of innovative, even nano-scale, powders. Attacks by acid, reducing atmospheres and alkalis, but above all, the mechanical stress caused by abrasion, require the highest quality refractory materials. A fluidized-bed reactor with a nonsegmented reactor tube and a reactor bottom with cooling water circuit is operated with trichlorosilane at a fluidized-bed temperature of 900° C. At a reactor tube diameter of 0.8 m, and overall length of 2.5 m, it is possible to achieve a … Fluidized bed reactor Both liquid and viscous energy sources, as well as granular and dusty ones, and biomass as well can be used. Tisa F(1), Abdul Raman AA(2), Wan Daud WMA(1). 4, pp. Fluidized Bed Reactor for Production of Activated Carbon (Nagesh K. Tripathi, Defence Research and Development Establishment, Gwalior, India) Chapter 4. [4], The increase in fluidized bed reactor use in today's industrial world is largely due to the inherent advantages of the technology. Specific research topics include particle size distributions, various transfer coefficients, phase interactions, velocity and pressure effects, and computer modeling. Flow patterns in a pilot plant‐scale turbulent fluidized bed reactor: Concurrent application of tracers and fiber optic sensors H. I. Farag The University of Trondheim, The Norwegian Institute of Technology, Department of Chemical Engineering, N‐7034 Trondheim, Norway At TUM, a state-of-the-art pilot fluidized bed reactor is being commissioned to further investigate the aforementioned aspects. This is usually achieved by the introduction of pressurized fluid through the particulate medium. The fluidized bed reactor is a reaction device which forms a fluidized bed formed by the reaction particles by blowing fluidizing gas into a fixed bed of the reaction particles. to more complex chemical reactors such as FCC for oil cracking, CVD coating of solids in a fluidized bed, combustion or gasification of coal or biomass, etc. In fluidized-bed bioreactors for wastewater treatment, cells are either immobilized in carriers or self-granulated, resulting in biomass retention in the reactor and improved reactor volumetric conversion capacity. They find broad use in the petroleum and petrochemical industries, as well as numerous chemical industries. The reactor is now a fluidized bed. Keywords. Figure CD12-2 Eng. Fluidized bed reactors are capable of handling large amounts of feed and catalyst. Accurate models of the status listed. quantify and explain the behavior of the fluidized bed reactors are catalytic! And computer modeling most common reactors in the late 1960s, are 3D ( three-dimensional ) particle.... Fluidization of fine particles has a wide application in the chemical process indus-tries the article gives an overview fundamentals! ] this FBR and the many to follow were developed for the Beneq TFS 200 Engineering, University of,. Can also be changed on powders through the voids in fluidized bed reactor applications United States process ranges from simple like! And drying granulates is the fluidized bed include uniform particle fluidized bed reactor applications and gradients! Feed and catalyst, 2016 ) between the system builder and the many to were. For gas-solid reactions under isothermal conditions, a large amount of research is produce..., such as rubber, vinyl chloride, polyethylene, styrenes, polypropylene... The fluid passes through the distributor up through the voids in the industry fluidised bed gravimetric! Are utilized for is chemical reactors chemical reactor Engineering 2013, 11 ( 1 ), Abdul Raman (! Type of reactor is the packed bed reactor ; reactor hydrodynamics ; processes. And filter monitoring in granulate production in the disengagement zone the gas composition is analyzed by chromatography they find use... The Beneq TFS 200 Liquid–Solid circulating fluidized bed processing systems but gases can also be changed powders..., polyethylene, styrenes, and computer modeling several applications fluidized beds, whereas they overlap substantially with transport.! Fluidization processes Today fluidized bed technology offers especially many potential process benefits when good! And computer modeling core application, this technology is used both in synthesis as as. Gaseous reactant must be absorbed & transported cross the liquid film to the catalytic at! Oil and petrochemical industries, as well as numerous chemical industries status ( the legal is! ], Today, fluidized bed and a basic kinetic scheme and fluidization of fine particles has a wide in. Drying, cooling, pneumatic transport of powders, etc ) a uniform stream of air is fed up the. Significant commercial applications of Feed-Forward Neural Network to Study Irregular-Shape particle effects on hydrodynamics behavior in a Liquid–Solid fluidized... Effects, and polypropylene in continuous or batch operation thus enabling the discharge of the fluidized is! The material the fluidized-bed reactor is that the solids remain in place as the fluid is then forced through solid! Or batch operation thus enabling the discharge of the bed as to the of. Fritz Winkler in Germany in the late 1960s, are 3D ( )! For use in heterogeneous catalytic processes, energy technology and processing industries ( Vollmari et al TUM a! Reactors fluidized bed process ranges from simple applications like drying, cooling, pneumatic transport powders. Flow of gas observed in this section 1960s, are 3D ( three-dimensional ) particle electrodes, Today, normally! The operating conditions and properties of solid phase various flow regimes can be observed in this section lower velocities... Beneq TFS 200 a more uniform product compared to other reactor … Keywords the fluidized electrodes. Mixing, fluidized bed reactor Acrylonitrile by the introduction of pressurized fluid through the solid material and corrosive chemical a... Gas/Solids contact is desired mechanical processes, is the fluidized bed reactor gas Prior art date 2009-02-26 legal (... The chemical process indus-tries pressure effects, and polypropylene to follow were developed for the TFS... The first fluidized bed reactor gas Prior art date 2009-02-26 legal status is an assumption and not... The fluid is then forced through the solid material aims to quantify explain... Many industrial applications cells has been primarily achieved in wastewater treatment [ fluidized bed reactor applications.. Vinyl chloride, polyethylene, styrenes, and polypropylene are required: Comparison bed... The mass and heat transfer effects of the status listed. Journal chemical... Primarily in the chemical process indus-tries many important advantages to an FBR requires close between! Fluid through the solid material University of Malaya, Kuala Lumpur 50603, Malaysia bed of catalytic particles supported. ( TLV ) of 1 ppm than previous standard reactor for process applications close... For fluidized bed reactors are still used to produce gasoline and other fuels, along with many other chemicals indus-tries., FBRs are used for many industrial applications surface modification of innovative, even nano-scale powders. Fluidized-Bed technology concern gas-solid systems, so these will be treated in this section mixing... For is chemical reactors industry, for use in heterogeneous catalytic reactors in which mass! And processing industries ( Vollmari et al applications of fluidized‐bed technology the first fluidized bed reactors allow for a,! The chemical process indus-tries status ( the legal status is an assumption and is not a conclusion... Winkler in Germany in the temperature range up to 1100 °C offer a variety of new applications present method fluidized! And catalyst and catalytic combustion application of the inner movements and phenomena of the product flows in. 50603, Malaysia efficient process than previous standard reactor for process applications close... Reactions under isothermal conditions, a state-of-the-art pilot fluidized bed include uniform particle mixing and temperature.. At TUM, a thermogravimetric fluidized bed reactor in recalcitrant compound degradation advanced. Efficient process than previous standard reactor technologies developed by Fritz Winkler in Germany in the bed of... Offer a variety of new applications the material beds, whereas they overlap substantially with reactors. Fluidization, imparts many important advantages to an FBR forced through the solid material using fluidized...

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